Posted by
Nanoencryption
on
- Get link
- Other Apps
Miller Indices (Planes and Directions) contd....
In this lecture, we will discuss Miller indices, and we will continue some part of the previous ones before we move on to the Miller indices for directions.
In the last lecture, we are talking about Miller indices for planes and directions. Now, this is needed to complete the description of the unit cell. So, for plane Miller indices are usually described as (h k l), and for the direction, you would describe the Miller indices as [u v w].
As we saw that for a plane, the procedure is ( h k l) are nothing but the reciprocal of the intercepts on respective unit cell lengths and which are converted to the smallest set of integers. So, h k l all three are integers; they can be positive as well as negative.
So, what this means is that you have intercept on the x-axis as 1, along with minus y-axis you have half, and along plus z-axis, you have one-third. The problem is that you cannot choose this origin and the and the thing Miller indices is that that the planes and direction should be represented within one unit cell. So, in this case, what you need to do is that you need to shift your origin.
So, I can represent these planes by these curled brackets, {1 0 0}, which means the family of (1 0 0) type planes, but only valid for a cubic system. So, {1 0 0} implies (1 0 0), (0 1 0) and (0 0 1). So, likewise, you can see that there is a multiplicity, in case of cube 1 0 0 implies; you also have (1̅ 0 0), (0 1̅ 0), and (0 0 1̅). So, you have depending on how you look at it, there are three different types of which are identical. Similarly, if you look at {1 1 0}, there are 12 different types of which are identical.
Similary, {1 1 1} implies,
So, the formula, dhkl is valid only for cubic, and that is,
For the tetragonal system, dhkl is,For orthorhombic system, dhkl is, The formula looks very similar to these three are orthogonal systems. For non-orthogonal systems, different dhkl are different. So, if you look at interplanar angles, they will also be different, so how to find the interplanar spacing and how to find the interplanar angles?.The representation (h k l) is independent of the crystal system. The multiplicity may change, but how you determine a plane, how you draw a plane that is independent of the crystal system. So, that is applied to all the crystal systems as long as you have a unit cell.
Let me draw a cubic unit cell, and I want to represent direction [1 2 3]. So, we have 1 intercept along the x-axis, intercepting along the y-axis at 2, and along the z-axis, it is 3. That is how you will represent a vector. So, this is the origin (O); you will have one step along the x-axis, two steps along the y-axis, and three steps along the z-axis. So, you will go out of the unit cell, which is not desirable. What we want to do instead is, convert the intercept values by dividing with the largest integer. So as per our previous example, which is 1/3, 2/3, and 1. Now you connect with the endpoint. So, this is the direction OA, nothing but [1 2 3]. So, a single direction is determined by these square brackets, and family of direction is given as <u v w>.
We will finish this lecture here, and in the next lecture, we look at some more examples of how do we draw the directions. Moreover, we will also look at a little different system, which is a hexagonal system. In a hexagonal system, the directions and planes are can be drawn in a different manner because the depiction of them can be done in four digits rather than three digits. Because as we will see hexagonal system can also be characterized by four-axis, and which can be reduced to three axes, but the fourth axis is drawn just for the sake of convenience, which is related to the two axes. So, there is a third axis in the basal plane of the hexagonal system.
For Next Lecture Click below
Structure of Materials : Bonding in Materials
Structure of Materials : Correlation between bond and physical propertiesCrystal Structure: Lattice and Basis
Primitive and Non-primitive Lattices
Crystal Systems and Bravais Lattice
Bravais Lattices Symmetry in Crystals
Symmetry and Correlations with the Bravais Lattices
Miller Indices (Planes and Directions)
Thank you very much
Click Here : Please Subscribe, Like and Share my channel
Comments
Post a Comment